Show simple item record

Selective access to dihydrophenanthridines and phenanthridinones via cyclisation of aryl amines onto N-tethered arynes.

dc.contributor.authorSun, W
dc.contributor.authorUttendorfer, M
dc.contributor.authorIdiris, FIM
dc.contributor.authorWerling, AYR
dc.contributor.authorSiddiq, K
dc.contributor.authorJones, CR
dc.date.accessioned2023-10-13T08:55:42Z
dc.date.available2023-10-13T08:55:42Z
dc.date.issued2023-09-15
dc.identifier.urihttps://qmro.qmul.ac.uk/xmlui/handle/123456789/91301
dc.description.abstract5,6-Dihydrophenanthridines are prepared from aryl amines via intramolecular addition to N-tethered arynes under mild conditions. A new o-silylaryl triflate precursor was developed to increase reactivity and enable electron-rich and electron-poor aryl amines to undergo cyclisation. A complete switch in product selectivity occurs when the reaction is conducted in air, affording the corresponding phenanthridin-6(5H)-one as the sole product under otherwise identical reaction conditions.en_US
dc.languageeng
dc.publisherRoyal Society of Chemistryen_US
dc.relation.ispartofChem Commun (Camb)
dc.rightsThis item is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
dc.rightsAttribution 3.0 United States*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/us/*
dc.titleSelective access to dihydrophenanthridines and phenanthridinones via cyclisation of aryl amines onto N-tethered arynes.en_US
dc.typeArticleen_US
dc.rights.holder© 2023 The Author(s). Published by Royal Society of Chemistry
dc.identifier.doi10.1039/d3cc03027j
pubs.author-urlhttps://www.ncbi.nlm.nih.gov/pubmed/37712932en_US
pubs.notesNot knownen_US
pubs.publication-statusPublished onlineen_US
rioxxterms.funderDefault funderen_US
rioxxterms.identifier.projectDefault projecten_US


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record

This item is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
Except where otherwise noted, this item's license is described as This item is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.