dc.contributor.author | Han, Shou | |
dc.date.accessioned | 2017-05-19T12:05:37Z | |
dc.date.available | 2017-05-19T12:05:37Z | |
dc.date.issued | 2016-09-28 | |
dc.date.submitted | 2017-05-16T12:36:25.045Z | |
dc.identifier.citation | Shou, H. 2016. Magnetism in Multiferroics and Low Dimensional Metal-Organic Complexes. Queen Mary University of London | en_US |
dc.identifier.uri | http://qmro.qmul.ac.uk/xmlui/handle/123456789/23198 | |
dc.description | PhD | en_US |
dc.description.abstract | Multiferroics and magnetic metal-organic complexes are candidates for sophisticated applications in the future. In thisthesis, the magnetism in BiFeO3 (a multiferroic
material with an incommensurate spin cycloidal structure), copper guanidiniam formate
(a multiferroic metal-organic complex with a one-dimensional magnetic structure) and
CP -RE-COT (a series of \zero-dimensional" single molecule magnets) are discussed.
A radio-frequency plasma sputtering thin lm deposition system and a ferroelectric
characterisation system were developed for the study of BiFeO3 epitaxial thin lms. A
large leakage current was observed in BiFeO3 thin lms, which hindered the investigations
on the ferroelectric properties and magnetoelectric coupling in them. An evidence
of the spin cycloid in a BiFeO3 thin lm was observed by grazing-incidence small angle
neutron scattering.
The magnetism of a multiferroic metal-organic complex with a one-dimensional
magnetic chain, [C(NH2)3][Cu(HCOO)3], was studied by magnetometry and muon spin
spectroscopy. A spin-canted antiferromagnetic order and critical phenomenon in this
material were investigated. It was shown that this material possessed an 3D Heisenberg
long-range order below 4.6K. The one-dimensional magnetic chain was also studied by
muon spin spectroscopy. The correlation length was measured with a eld dependence
of H��1.
Magnetisation relaxations of a series of single molecule magnets CP -RE-COT (COT
= C8H8- CP = C5Me, which show \zero-dimensional" magnetism, were studied
using an AC magnetometer and muon spin spectroscopy. Three possible relaxation
pathways, including a quantum tunnelling process and two Orbach relaxation processes,
were suggested by the relaxation behaviour. The suppression of the quantum
tunnelling effect resulting from the entanglement of the ground states, which probably
arises from the exchange interactions in CP -RE-COT, was also observed with a 1000
Oe applied magnetic eld. Data that were consistent with long-range magnetic ordering
was observed in CP -Dy-COT, which would be the fi rst ever report of long-range
magnetic order in a single ion magnet. | en_US |
dc.description.sponsorship | Thanks Chinese scholarship council
Queen Mary, University of London | en_US |
dc.language.iso | en | en_US |
dc.publisher | Queen Mary University of London | en_US |
dc.rights | The copyright of this thesis rests with the author and no quotation from it or information derived from it may be published without the prior written consent of the author | |
dc.subject | Physics | en_US |
dc.subject | Condensed matter | en_US |
dc.subject | Multiferroics | en_US |
dc.subject | metal-organic complexes | en_US |
dc.title | Magnetism in Multiferroics and Low Dimensional Metal-Organic Complexes | en_US |
dc.type | Thesis | en_US |