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dc.contributor.authorYang, Cen_US
dc.contributor.authorBrazhkin, VVen_US
dc.contributor.authorDove, MTen_US
dc.contributor.authorTrachenko, Ken_US
dc.date.accessioned2015-03-26T11:44:29Z
dc.date.available2014-12-19en_US
dc.date.issued2015-01en_US
dc.identifier.urihttp://qmro.qmul.ac.uk/xmlui/handle/123456789/7123
dc.description.abstractA new dynamic line, the Frenkel line, has recently been proposed to separate the supercritical state into rigid-liquid and nonrigid gaslike fluid. The location of the Frenkel line on the phase diagram is unknown for real fluids. Here we map the Frenkel line for three important systems: CO(2), H(2)O, and CH(4). This provides an important demarcation on the phase diagram of these systems, the demarcation that separates two distinct physical states with liquidlike and gaslike properties. We find that the Frenkel line can have a similar trend as the melting line above the critical pressure. Moreover, we discuss the relationship between unexplained solubility maxima and Frenkel line, and we propose that the Frenkel line corresponds to the optimal conditions for solubility.en_US
dc.format.extent012112 - ?en_US
dc.languageengen_US
dc.relation.ispartofPhys Rev E Stat Nonlin Soft Matter Physen_US
dc.subjectCarbon Dioxideen_US
dc.subjectMethaneen_US
dc.subjectMolecular Dynamics Simulationen_US
dc.subjectPhase Transitionen_US
dc.subjectPressureen_US
dc.subjectSolubilityen_US
dc.subjectTemperatureen_US
dc.subjectWateren_US
dc.titleFrenkel line and solubility maximum in supercritical fluids.en_US
dc.typeArticle
dc.identifier.doi10.1103/PhysRevE.91.012112en_US
pubs.author-urlhttps://www.ncbi.nlm.nih.gov/pubmed/25679575en_US
pubs.issue1en_US
pubs.notesNot knownen_US
pubs.organisational-group/Queen Mary University of London
pubs.organisational-group/Queen Mary University of London/Faculty of Science & Engineering
pubs.organisational-group/Queen Mary University of London/Faculty of Science & Engineering/Physics and Astronomy
pubs.organisational-group/Queen Mary University of London/REF
pubs.organisational-group/Queen Mary University of London/REF/REF - UoA 09
pubs.publication-statusPublisheden_US
pubs.volume91en_US


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