Novel scalable aerosol-assisted CVD route for perovskite solar cells
dc.contributor.author | RATNASINGHAM, SR | |
dc.contributor.author | Mohan, L | |
dc.contributor.author | Dabaczi, M | |
dc.contributor.author | Degousee, T | |
dc.contributor.author | Binions, R | |
dc.contributor.author | Fenwick, O | |
dc.contributor.author | Kim, J-S | |
dc.contributor.author | McLachlan, M | |
dc.contributor.author | Briscoe, J | |
dc.date.accessioned | 2021-02-18T10:36:10Z | |
dc.date.available | 2021-02-04 | |
dc.date.available | 2021-02-18T10:36:10Z | |
dc.date.issued | 2021-01 | |
dc.identifier.uri | https://qmro.qmul.ac.uk/xmlui/handle/123456789/70404 | |
dc.description.abstract | Organo-metal halide perovskite research has progressed rapidly, with photovoltaic (PV) devices achieving over 25% power conversion efficiency (PCE). However, scalable production of these devices is an ongoing challenge. We demonstrate the growth of methylammonium lead triiodide (MAPI) films via a novel two-step aerosol-assisted chemical vapour deposition (AACVD) method leading to the first ever perovskite-based PV devices using active layers deposited by AACVD. This is a scalable deposition process, requiring less complex equipment than conventional CVD. Furthermore, our method utilises methanol (MeOH) as the only solvent, as opposed to harmful solvents typically used in perovskite processing. Structural and optical characterization confirms successful formation of MAPI with no secondary phases and an optical bandgap of ~ 1.58 eV. The final film had large grains (2-10 µm), with thickness ranging from 500-1100 nm. These films were used to fabricate working PV devices resulting in a champion PCE of 5.4 %. While films demonstrated high structural and compositonal quality, we identified large film roughness as a limiting factor in device PCE, and elucidate the origin of this via detailed study of the film growth, which reveals a unique multi-step film formation process. | en_US |
dc.publisher | Royal Society of Chemistry | en_US |
dc.relation.ispartof | Materials Advances | |
dc.rights | This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. | |
dc.rights | Attribution 3.0 United States | * |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/us/ | * |
dc.title | Novel scalable aerosol-assisted CVD route for perovskite solar cells | en_US |
dc.type | Article | en_US |
dc.rights.holder | © 2021, The Author(s) | |
dc.identifier.doi | 10.1039/D0MA00906G | |
pubs.notes | Not known | en_US |
pubs.publication-status | Accepted | en_US |
dcterms.dateAccepted | 2021-02-04 | |
rioxxterms.funder | Default funder | en_US |
rioxxterms.identifier.project | Default project | en_US |
Files in this item
Files | Size | Format | View |
---|---|---|---|
There are no files associated with this item. |
This item appears in the following Collection(s)
Except where otherwise noted, this item's license is described as This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.