dc.contributor.author | Milita, S | en_US |
dc.contributor.author | Liscio, F | en_US |
dc.contributor.author | Cowen, L | en_US |
dc.contributor.author | Cavallini, M | en_US |
dc.contributor.author | Drain, BA | en_US |
dc.contributor.author | Degousée, T | en_US |
dc.contributor.author | Luong, S | en_US |
dc.contributor.author | Fenwick, O | en_US |
dc.contributor.author | Guagliardi, A | en_US |
dc.contributor.author | Schroeder, BC | en_US |
dc.contributor.author | Masciocchi, N | en_US |
dc.date.accessioned | 2020-01-23T11:23:33Z | |
dc.date.available | 2020-01-14 | en_US |
dc.date.issued | 2020-01-16 | en_US |
dc.identifier.issn | 2050-7526 | en_US |
dc.identifier.uri | https://qmro.qmul.ac.uk/xmlui/handle/123456789/62502 | |
dc.description.abstract | The long-known class of compounds called naphthalene diimides (NDI), bearing alkyl subtituents on the imide nitrogen atoms, have been widely used as active materials in thin film devices with interesting optical, sensing and electrical applications. Less is known about their rich crystal chemical behaviour, which comprises numerous polymorphic transitions, and the occurrence of elusive liquid crystalline phases. It is this behaviour which determines the response of the devices based on them. Here we fully characterized, by combining a combination of differential scanning calorimetry, powder and thin film diffraction and optical microscopy techniques, two newly synthetized NDI materials bearing n-octyl and n-decyl side-chains, as well as lighter analogues, of known room temperature crystal structures. In search for a rationale of their physico-chemical properties, phase stability and thermally induced solid-state transition reversibility, the differential behaviour of these NDI materials is here interpreted based on the competitive role of intermolecular pi-pi interactions and of the alkyl chains flexibility. The occurrence of comparable local minima of the molecular conformational energy hypersurface for shorter alkyls, and, for longer ones, of rotator phases, is here invoked. | en_US |
dc.language | en | en_US |
dc.publisher | Royal Society of Chemistry | en_US |
dc.relation.ispartof | Journal of Materials Chemistry C | en_US |
dc.rights | This is a pre-copyedited, author-produced version of an article accepted for publication in Journal of Materials Chemistry C following peer review. The version of record is available https://pubs.rsc.org/en/Content/ArticleLanding/2020/TC/C9TC06967D#!divAbstract | |
dc.title | Polymorphism in N,N′-dialkyl-naphthalene diimides | en_US |
dc.type | Article | |
dc.rights.holder | © Royal Society of Chemistry 2020 | |
dc.identifier.doi | 10.1039/c9tc06967d | en_US |
pubs.notes | Not known | en_US |
pubs.publication-status | Published | en_US |
dcterms.dateAccepted | 2020-01-14 | en_US |
rioxxterms.funder | Default funder | en_US |
rioxxterms.identifier.project | Default project | en_US |
qmul.funder | Organic thermoelectrics in multiple structural and transport regimes::Royal Society | en_US |
qmul.funder | Organic thermoelectrics in multiple structural and transport regimes::Royal Society | en_US |