dc.contributor.author | Katsina, T | en_US |
dc.contributor.author | Sharma, SP | en_US |
dc.contributor.author | Buccafusca, R | en_US |
dc.contributor.author | Quinn, DJ | en_US |
dc.contributor.author | Moody, TS | en_US |
dc.contributor.author | Arseniyadis, S | en_US |
dc.date.accessioned | 2019-11-19T10:17:17Z | |
dc.date.available | 2019-11-07 | en_US |
dc.date.issued | 2019-12-06 | en_US |
dc.identifier.uri | https://qmro.qmul.ac.uk/xmlui/handle/123456789/61439 | |
dc.description.abstract | A straightforward synthesis of α-substituted acrylonitriles is described using 4-cyano-3-oxotetrahydro-thiophene (c-THT) as an acrylonitrile surrogate. This unprecedented two-step sequence featuring a palladium-catalyzed allylic alkylation (Pd-AA) and a retro-Dieckmann fragmentation provides a general entry into diversely substituted 1,4-dienes. | en_US |
dc.format.extent | 9348 - 9352 | en_US |
dc.language | eng | en_US |
dc.relation.ispartof | Org Lett | en_US |
dc.rights | This is a pre-copyedited, author-produced version of an article accepted for publication in Organic Letters following peer review. The version of record is available https://pubs.acs.org/doi/10.1021/acs.orglett.9b03522 | |
dc.title | Sequential Palladium-Catalyzed Allylic Alkylation/retro-Dieckmann Fragmentation Strategy for the Synthesis of α-Substituted Acrylonitriles. | en_US |
dc.type | Article | |
dc.rights.holder | Copyright © 2019 American Chemical Society | |
dc.identifier.doi | 10.1021/acs.orglett.9b03522 | en_US |
pubs.author-url | https://www.ncbi.nlm.nih.gov/pubmed/31710491 | en_US |
pubs.issue | 23 | en_US |
pubs.notes | Not known | en_US |
pubs.publication-status | Published | en_US |
pubs.volume | 21 | en_US |
rioxxterms.funder | Default funder | en_US |
rioxxterms.identifier.project | Default project | en_US |