Field-induced single-ion magnetic behaviour in a highly luminescent Er<sup>3+</sup> complex
View/
DOI
10.1016/j.matchemphys.2015.04.059
Journal
Materials Chemistry and Physics
ISSN
0254-0584
Metadata
Show full item recordAbstract
The magnetic properties of a perfluorinated Er<sup>3+</sup> complex, with record luminescent properties, have been investigated. [Er(F-TPIP)<inf>3</inf>] displays thermally activated slow relaxation of the magnetisation under an applied H<inf>DC</inf> field of 500Oe. The effective relaxation barrier E<inf>eff</inf> is found to be 26.8K (18.6cm<sup>-1</sup>). At zero static field, efficient quantum tunnelling of the magnetization occurs.
Authors
Coutinho, JT; Pereira, LCJ; Martín-Ramos, P; Ramos Silva, M; Zheng, YX; Liang, X; Ye, HQ; Peng, Y; Baker, PJ; Wyatt, PB; Gillin, WPCollections
Language
Licence information
Copyright statements
