dc.contributor.author | Viswanathan, M | en_US |
dc.date.accessioned | 2019-06-21T09:18:36Z | |
dc.date.available | 2018-07-03 | en_US |
dc.date.issued | 2018-08-29 | en_US |
dc.identifier.uri | https://qmro.qmul.ac.uk/xmlui/handle/123456789/58158 | |
dc.description.abstract | Copper guanidinium formate (CuGF) is an ABX3-type metal-organic framework bearing a polar space group, housing a guest-host connectivity between the guanidinium and formate ions. With the maiden data-set based on single-crystal neutron diffraction, we report the discovery of the guest orderliness which surprisingly accommodates an enhancement for low-symmetric CuGF, while the scenario is contrasting for the high-symmetric Mn cousin. We provide an in-depth evaluation of the inter-guanidinium scheme and thus propose the mechanism behind this unusual effect. | en_US |
dc.format.extent | 21809 - 21813 | en_US |
dc.language | eng | en_US |
dc.relation.ispartof | Phys Chem Chem Phys | en_US |
dc.title | Enhancement of the guest orderliness in a low-symmetric perovskite-type metal-organic framework influenced by Jahn-Teller distortion. | en_US |
dc.type | Article | |
dc.rights.holder | © 2018 Royal Society of Chemistry | |
dc.identifier.doi | 10.1039/c8cp03886d | en_US |
pubs.author-url | https://www.ncbi.nlm.nih.gov/pubmed/30118132 | en_US |
pubs.issue | 34 | en_US |
pubs.notes | Not known | en_US |
pubs.publication-status | Published | en_US |
pubs.volume | 20 | en_US |
rioxxterms.funder | Default funder | en_US |
rioxxterms.identifier.project | Default project | en_US |