dc.contributor.author | MARINAKIS, S | en_US |
dc.contributor.author | Howard,, B | en_US |
dc.date.accessioned | 2015-12-01T11:22:49Z | |
dc.date.issued | 2015-12-14 | en_US |
dc.date.submitted | 2015-11-30T14:13:03.806Z | |
dc.identifier.uri | http://qmro.qmul.ac.uk/xmlui/handle/123456789/9478 | |
dc.description.abstract | We use both experiments and theory to study nitric oxide complexes. On the experimental side, we introduce a mixture of nitric oxide with other gases, such as krypton, carbon monoxide, water and benzene, into a high vacuum chamber through a pulsed nozzle. The pulsed nozzle is used to create a supersonic expansion, and to transfer the molecules into the lowest vibrational and rotational levels. The low pressure in our chamber, which is typically a hundred thousand times less than the atmospheric pressure, excludes the possibility of creating complexes of more than two molecules. A high-power pulsed microwave field polarizes the nitric oxide complexes created in this way, and after some microseconds we detect the emission. This emission carries valuable information about the structure and the function of the complexes. On the theoretical side, we use commercial and home-made programs to calculate the intermolecular forces and the energy levels. Comparing our experimental and theoretical results enables us to improve our theoretical models and explain our often complicated microwave spectra. | en_US |
dc.description.sponsorship | We acknowledge EPSRC Grant No. EP/H008403/1 awarded to Professor Brian J. Howard (Oxford University), the Centre for Public Engagement (Queen Mary, University of London) for funding, and Lis Carter for help in the recording. | en_US |
dc.format.medium | MP3 Podcast | |
dc.format.medium | MP3 Podcast | |
dc.format.medium | MP3 Podcast | |
dc.format.medium | MP3 Podcast | en_US |
dc.language | English | en_US |
dc.language.iso | en | en_US |
dc.relation.ispartof | Microwave studies of nitrosyl complexes | en_US |
dc.relation.ispartofseries | Microwave studies of nitrosyl complexes; | |
dc.rights | You may not, without prior permission upload this Podcast to another website. | |
dc.subject | microwave spectra | en_US |
dc.subject | supersonic expansion | en_US |
dc.subject | nitric oxide complexes | en_US |
dc.subject | intermolecular forces | en_US |
dc.title | Experimental and theoretical approaches | en_US |
dc.rights.holder | (c) 2015 Marinakis, S and Howard, B | |
dc.identifier.doi | http://dx.doi.org/10.17636/01009478 | |
pubs.issue | Episode 4 | en_US |
pubs.notes | No embargo | en_US |