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dc.contributor.authorYe, Huanqing
dc.date.accessioned2015-10-05T13:45:41Z
dc.date.available2015-10-05T13:45:41Z
dc.date.issued2014
dc.identifier.citationYe, H. 2014. Organo-Sensitised Erbium System for Optical Amplification at Telecommunication Wavelength. Queen Mary University of London.en_US
dc.identifier.urihttp://qmro.qmul.ac.uk/xmlui/handle/123456789/9079
dc.descriptionPhDen_US
dc.description.abstractThe erbium-based optical amplifier (EDFA) plays a vital role in the global fibre-optic telecommunication network. However, there are two main issues with current EDFAs, their bulky size means that they cannot be integrated into silicon-based photonic devices, and they need high pump power to produce optical gain. Here, a potential organo-erbium gain system has been invented, which could be operated under a low pump power and integrated onto a silicon-based device. The fully-fluorinated organic erbium complex [Er(ftpip)3] was mixed with a fully-fluorinated organic zinc complex [Zn(F-BTZ)2], acting as a chromophore over the visible range. The composite provides extraordinary sensitisation from the Zn(F-BTZ)2 to Er(ftpip)3 over a broad-visible band, which is compatible with high power LEDs, whilst the erbium ions have a new record of IR emission lifetime of ~ 0.8 ms (quantum yield = ~ 7%). The integrated sensitisation is ~ 104 times that of the intrinsic excitation into erbium. This system has been integrated into an organic light emitting diodes (OLEDs) demonstrating that the energy transfer is dominated by triplet states of the Zn(F-BTZ)2. This is used for explaining the photoluminescence saturation and large pump-rate, with the composite being excited by a low power diode laser on the chromophore units. This composite-system was used to fabricate a slab waveguide, in which an relative gain of 3.4 dB/cm was achieved when excited by a diode laser with 3 mW. A microscopic-optic setup was designed to measure IR line strengths of erbium ions in crystals of complexes, which were included in theoretical calculation to obtain accurate quantum yield for IR emission of erbium ions. The inclusion of IR line strengths measured from crystals is found to be crucial for Judd-Ofelt parameterisation on organic erbium complexes. It was demonstrated that fluorination could increase the line strengths of hypersensitive transitions and IR transition for 1.5 μm band.en_US
dc.language.isoenen_US
dc.publisherQueen Mary University of Londonen_US
dc.subjectPhysicsen_US
dc.subjectErbiumen_US
dc.subjectErbium-based optical amplifieren_US
dc.subjectFibre-optic telecommunicationsen_US
dc.titleOrgano-Sensitised Erbium System for Optical Amplification at Telecommunication Wavelength.en_US
dc.typeThesisen_US
dc.rights.holderThe copyright of this thesis rests with the author and no quotation from it or information derived from it may be published without the prior written consent of the author


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