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dc.contributor.authorWood, MHen_US
dc.contributor.authorWelbourn, RJLen_US
dc.contributor.authorZARBAKHSH, Aen_US
dc.contributor.authorGutfreund, Pen_US
dc.contributor.authorClarke, SMen_US
dc.date.accessioned2015-08-14T13:46:42Z
dc.date.available2015-06-07en_US
dc.date.issued2015-06-07en_US
dc.identifier.issn1520-5827en_US
dc.identifier.urihttp://qmro.qmul.ac.uk/xmlui/handle/123456789/8163
dc.description.abstractPolarized neutron reflectometry has been used to investigate the detailed adsorption behavior and corrosion inhibition mechanism of two surfactants on a nickel surface under acidic conditions. Both the corrosion of the nickel surface and the structure of the adsorbed surfactant layer could be monitored in situ by the use of different solvent contrasts. Layer thicknesses and roughnesses were evaluated over a range of pH values, showing distinctly the superior corrosion inhibition of one negatively charged surfactant (sodium dodecyl sulfate) compared to a positively charged example (dodecyl trimethylammonium bromide) due to its stronger binding interaction with the surface. It was found that adequate corrosion inhibition occurs at significantly less than full surface coverage.en_US
dc.format.extent7062 - 7072en_US
dc.languageEnglishen_US
dc.language.isoenen_US
dc.publisherAmerican Chemical Societyen_US
dc.relation.ispartofLangmuir: the ACS journal of surfaces and colloidsen_US
dc.rightsThis is an open access article published under a Creative Commons Attribution (CC-BY) License, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
dc.subjectCorrosion inhibitorsen_US
dc.titlePolarized Neutron Reflectometry of Nickel Corrosion Inhibitorsen_US
dc.typeArticle
dc.rights.holder(c) 2015 The American Chemical Society
dc.identifier.doi10.1021/acs.langmuir.5b01718(2015)en_US
pubs.issue25en_US
pubs.notesNot knownen_US
pubs.publication-statusPublisheden_US
pubs.publisher-urlhttp://pubs.acs.org/en_US
pubs.volume31en_US
dcterms.dateAccepted2015-06-07en_US


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