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Total Synthesis of Putative 11-epi-Lyngbouilloside Aglycon
(Frontiers Media, 2016-08-09)
Total Synthesis of Nominal Lyngbouilloside Aglycon
Palladium-Catalyzed Asymmetric Allylic Alkylation of 4-Substituted Isoxazolidin-5-ones: Straightforward Access to β2,2 -Amino Acids.
We report here an unprecedented and highly enantioselective palladium-catalyzed allylic alkylation applied to 4-substituted isoxazolidin-5-ones. Ultimately, the process provides a straightforward access to β2,2 -amino acids ...